本论文的主要目的在于研究常规溶液法组装的配位聚合物的结构。合成了三种新颖结构的配位聚合物单晶体:[Ni(H2O)6][C6H2(COO)2(COOH)2](1)、Mn(H2O)6][C6H2(COO)2(COOH)2](2)和[Cu(H2O)3][C6H2(COO）2（CO0H)2]·2H2O (3)。对配合物1和2做了元素分析、红外光谱和 X 一射线单晶行射;对配合物3做了元素分析、红外光谱、XRPD分析，并推测了其结构。本文所合成的配合物晶体中存在氢键和静电作用，这些分子间的弱相互作用对于配合物的晶体结构具有明显稳定作用，并通过氢键可将配合物分子扩展成为三维网状结构。

The aim of this paper is to study the structure of coordination polymers synthesized by means of solvent way. Three coordination polymers with novel structures have been synthesized: [Ni(H2O)6] [C6H2(COO)2(COOH)2](1)、[Mn(H2O)6][C6H2(COO)2(COOH)2](2)and [Cu(HzO)3][C6H2(COO)2- (COOH)2]·2H2O(3).The coordination polymers 1 and 2 were characterized by means of elemental analysis, IR and X-ray single crystal diffraction. The coordination polymers 3 were characterized by means of elemental analysis, IR and XRPD analysis, and their structures were speculated. There were electrostatic interactions and hydrogen bonds in these complexes crystals. These intermolecular weak interactions can stabilize the crystal structure of the complexes.These complex molecules can also form three-dimensional networks structure by means of these hydrogen bonds.