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中文题名:

 电子辐射GaInP/GaAs/Ge太阳电池温度及功率变化光致发光研究    

姓名:

 刘晏妤    

保密级别:

 公开    

论文语种:

 中文    

学科代码:

 082703    

学科专业:

 核技术及应用    

学生类型:

 硕士    

学位:

 工学硕士    

学位类型:

 学术学位    

学位年度:

 2021    

校区:

 北京校区培养    

学院:

 核科学与技术学院    

第一导师姓名:

 王荣    

第一导师单位:

 北京师范大学核科学与技术学院    

提交日期:

 2021-06-09    

答辩日期:

 2021-05-13    

外文题名:

 Temperature and excitation power dependent photoluminescence analysis of electron-irradiated GaInP/GaAs/Ge solar cells    

中文关键词:

 电子辐射 ; GaInP/GaAs/Ge三结太阳电池 ; 光致发光 ; 热淬灭效应 ; 反淬灭效应    

外文关键词:

 Electron irradiation ; GaInP/GaAs/Ge triple-junction solar cells ; Photoluminescence ; Thermal quenching effect ; Abnormal thermal quenching effect    

中文摘要:

       本文以注量为 5×1014cm-2,能量为 1.0 MeV电子辐射 GaInP/GaAs/Ge三结太阳电池为研究对象,对其进行了温度及功率变化光致发光谱测量,研究了电子辐射 GaInP 顶电池、GaAs 中间电池以及 Ge 底电池的热淬灭效应与反淬灭效应,并讨论了当温度从 10 K 升高至 300 K,各结子电池光生载流子辐射复合与非辐射复合的竞争机制。主要包括以下内容:
       (1)当温度从 10 K 升高至 300 K,测量了电子辐射 GaInP 顶电池、GaAs 中间电池以及 Ge 底电池温度变化 PL 光谱,鉴别出 GaInP 顶电池(Ev + 0.55 eV)、GaAs 中间电池(Ec -0.96 eV)以及 Ge 底电池(EC1 = 0.37 eV和 EC2 = 0.12 eV)的非辐射复合中心。
        (2)分析了电子辐射 GaInP 顶电池和 Ge 底电池温度变化 PL 光谱,鉴别出 GaInP 顶电池(????1 = 0.05???? 和 ????2 = 0.35????)的中间态能级。 (3)测量了电子辐射 GaInP 顶电池、GaAs 中间电池以及 Ge 底电池 的功率变化 PL 光谱,发现随着非辐射复合中心被热激活,Z 值从 1 逐渐 增大至 2,导致 PL 强度与激发功率从正比关系逐渐变成平方函数关系, 光生载流子非辐射复合方式增多,非辐射复合中心是引起三结太阳电池发生热淬灭效应的核心因素;随着中间态能级的出现,Z 值随温度升高减 小,光生载流子辐射复合方式增多,是 GaInP 顶电池和 Ge 底电池出现反淬灭效应的原因。 

外文摘要:

         Temperature and excitation power dependent photoluminescence measurements were presented for the electron-irradiated(1.0 MeV electron beams with a fluence of 5×1014cm-2)GaInP/GaAs/Ge triple-junction solar cells. The thermal quenching effect and abnormal thermal quenching effect of electron-irradiated GaInP top-cell, GaAs middle-cell and Ge bottom-cell were investigated. When the temperature goes from 10 K to 300 K, the competing mechanism of photo-generated carriers that between radiative recombination and non-radiative recombination in each sub-cell were obtained. The main research work includes:

        (1)When the temperature goes from 10 K to 300 K, the temperature dependent photoluminescence spectra of GaInP top-cell, GaAs middle-cell and Ge bottom-cell were presented respectively. The non-radiative recombination centers in GaInP top-cell(Ev + 0.55 eV), GaAs middle-cell(Ec -0.96 eV)and Ge bottom-cell(EC1 = 0.37 eV和 EC2 = 0.12 eV)were identified.

        (2)The temperature dependent photoluminescence spectra of GaInP top- cell and Ge bottom-cell were analyzed respectively. The intermediate states in GaInP top-cell(????1 = 0.05???? 和 ????2 = 0.35????)were identified. (3)The excitation power dependent photoluminescence spectra of GaInP top-cell, GaAs middle-cell and Ge bottom-cell were obtained, respectively. It was found that the Z-value increased from 1 to 2 with the activation of the non-radiative recombination center, which caused the relationship between  intensity and excitation power gradually changed from linear to quadratic dependence. As a result, the proportion of non-radiative recombination in recombination processes of photo-generated carriers increased, so the non-radiative recombination center is the core factor that causes the thermal quenching effect of the triple-junction solar cells. With the appearance of intermediate states, the Z-value decreased with the increase of temperature, and the proportion of radiative recombination in recombination processes of photo-generated carriers increased, which is the reason for the abnormal thermal quenching effect of GaInP top-cell and Ge bottom-cell. 

参考文献总数:

 59    

作者简介:

 以第一作者发表EI论文1篇;以第三作者及第四作者发表SCI论文2篇    

馆藏号:

 硕082703/21008    

开放日期:

 2022-06-09    

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