中文题名: | 电子辐射GaInP/GaAs/Ge太阳电池温度及功率变化光致发光研究 |
姓名: | |
保密级别: | 公开 |
论文语种: | 中文 |
学科代码: | 082703 |
学科专业: | |
学生类型: | 硕士 |
学位: | 工学硕士 |
学位类型: | |
学位年度: | 2021 |
校区: | |
学院: | |
第一导师姓名: | |
第一导师单位: | |
提交日期: | 2021-06-09 |
答辩日期: | 2021-05-13 |
外文题名: | Temperature and excitation power dependent photoluminescence analysis of electron-irradiated GaInP/GaAs/Ge solar cells |
中文关键词: | 电子辐射 ; GaInP/GaAs/Ge三结太阳电池 ; 光致发光 ; 热淬灭效应 ; 反淬灭效应 |
外文关键词: | Electron irradiation ; GaInP/GaAs/Ge triple-junction solar cells ; Photoluminescence ; Thermal quenching effect ; Abnormal thermal quenching effect |
中文摘要: |
本文以注量为 5×1014cm-2,能量为 1.0 MeV电子辐射 GaInP/GaAs/Ge三结太阳电池为研究对象,对其进行了温度及功率变化光致发光谱测量,研究了电子辐射 GaInP 顶电池、GaAs 中间电池以及 Ge 底电池的热淬灭效应与反淬灭效应,并讨论了当温度从 10 K 升高至 300 K,各结子电池光生载流子辐射复合与非辐射复合的竞争机制。主要包括以下内容: |
外文摘要: |
Temperature and excitation power dependent photoluminescence measurements were presented for the electron-irradiated(1.0 MeV electron beams with a fluence of 5×1014cm-2)GaInP/GaAs/Ge triple-junction solar cells. The thermal quenching effect and abnormal thermal quenching effect of electron-irradiated GaInP top-cell, GaAs middle-cell and Ge bottom-cell were investigated. When the temperature goes from 10 K to 300 K, the competing mechanism of photo-generated carriers that between radiative recombination and non-radiative recombination in each sub-cell were obtained. The main research work includes: (1)When the temperature goes from 10 K to 300 K, the temperature dependent photoluminescence spectra of GaInP top-cell, GaAs middle-cell and Ge bottom-cell were presented respectively. The non-radiative recombination centers in GaInP top-cell(Ev + 0.55 eV), GaAs middle-cell(Ec -0.96 eV)and Ge bottom-cell(EC1 = 0.37 eV和 EC2 = 0.12 eV)were identified. (2)The temperature dependent photoluminescence spectra of GaInP top- cell and Ge bottom-cell were analyzed respectively. The intermediate states in GaInP top-cell(????1 = 0.05???? 和 ????2 = 0.35????)were identified. (3)The excitation power dependent photoluminescence spectra of GaInP top-cell, GaAs middle-cell and Ge bottom-cell were obtained, respectively. It was found that the Z-value increased from 1 to 2 with the activation of the non-radiative recombination center, which caused the relationship between intensity and excitation power gradually changed from linear to quadratic dependence. As a result, the proportion of non-radiative recombination in recombination processes of photo-generated carriers increased, so the non-radiative recombination center is the core factor that causes the thermal quenching effect of the triple-junction solar cells. With the appearance of intermediate states, the Z-value decreased with the increase of temperature, and the proportion of radiative recombination in recombination processes of photo-generated carriers increased, which is the reason for the abnormal thermal quenching effect of GaInP top-cell and Ge bottom-cell. |
参考文献总数: | 59 |
作者简介: | 以第一作者发表EI论文1篇;以第三作者及第四作者发表SCI论文2篇 |
馆藏号: | 硕082703/21008 |
开放日期: | 2022-06-09 |