心环烯是构筑曲面富碳分子的常用结构基元。本文利用Diels-Alder和Scholl反应，成功合成了两种基于心环烯构筑的曲面分子CHH和CMH。X射线衍射实验证实了CHH和CMH的结构。CHH结构中心环烯通过一个七元环和两个六元环与两个HBC连接，心环烯和七元环使得CHH同时具有正曲率和负曲率，同时，扭曲的结构使得[5]螺烯具备更高的手性稳定性。CHH吸收光谱显示其在300 nm到650 nm的广泛吸收，荧光光谱显示CHH具有橙色的荧光 (λ_em = 576 nm) ，荧光量子产率为4.8%。借助手性高效液相色谱实现了CHH的光学拆分，光学纯的CHH的CD光谱呈现良好的镜像关系，在371 nm和510 nm处g_abs = 2.8 × 10^-3。CPL光谱显示，CHH在580 nm处，g_lum = 1.4 × 10^-3。在CMH的晶体中，CMH骨架中的心环烯通过六元环和HBC连接，凸面朝向CMP单元。与不带取代基的CMP的接近平面的构象相比，CMH中的CMP单元呈现椅式构象。在溶液中观察到了心环烯翻转过程，变温¹H NMR中，能够观察到信号的融合。吸收光谱显示CMH在300到500 nm的显著吸收，荧光光谱显示CMH具有绿色荧光 (λ_em = 491 nm) 。

Corannulene is widely used to construct curved carbon-rich molecule. Herein, two curved molecules (i.e., CHH and CMH) containing corannulene moiety were generated. Both CHH and CMH were confirmed by X-ray diffraction analysis. The corannulene on CHH is connected to two HBCs with a seven-membered ring and two six-membered rings. The corannulene and seven-membered rings give CHH both positive and negative curvature. Meanwhile, the twisted structure led [5]helicene with higher chiral stability. CHH show a wide absorption range from 300 to 650 nm, and orange fluorescence (λ_em = 576 nm); the fluorescence quantum yield as 4.8%. The optical separation of CHH was achieved via chiral HPLC, the CD spectra of optically pure CHH show a good mirror relation with g_abs as 2.8 × 10^-3 at 371 nm and 510 nm. CPL spectra showed that CHH displays glum = 1.4 × 10^-3 at 580 nm. In CMH, the corannulene connect HBC by a six-membered ring, with a convex surface toward the CMP unit. Compared with plan CMP without substituents, the CMP unit in CMH presents a chair conformation. The inversion process of corannulene was observed in solution, and the signal fusion was observed in ¹H NMR with variable temperature. CMH has absorption from 300 to 500 nm, and green fluorescence (λ_em = 491 nm).